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For any matter in any state the physio-chemical properties behave linearly inside sure range of reference. For instance foe a matter “X” the state of substance and its physio-chemical could be diversified only inside a certain restrict which might be particular to that substance. If we add a selected element to the matter “X” exterior that restrict the physio-chemical properties of the matter adjustments. When matter itself modifications then the spectral science may even change which might be different from the primary form matter. The extra the precise optical mannequin deviates from a easy propagation of the light wave in a homogeneous medium, the larger are the deviations from the Beer-Lambert legislation normally.
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Additionally, there are issues of self-quenching, inside filter effect, at high concentrations that introduce deviations. The reply by Manohar Sehgal provides a great overview of the restrictions.